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- W2912397109 abstract "The detection of ArH+ in the Crab nebula has led to speculation of other noble gas-containing molecules existing beyond the laboratory. Here, the previously unreported ArNH2+ molecule is shown through high-level coupled cluster theory quartic force field computations to possess a notable Ar–N bond strength (36.8 kcal/mol), a sizable dipole moment (2.78 D), near-prolate rotational character, and fairly bright vibrational transitions at 3256.0 cm−1 and 475.7 cm−1 on opposite ends of the infrared scale. Three of the other vibrational frequencies have observable intensities, and all of these data are provided for the three main isotopes of argon: 36ArNH2+, 38ArNH2+, and 40ArNH2+. These spectroscopic data should be useful in assisting any potential observations of the molecule whether in astrophysical or laboratory environments even if in the latter ArNH2+ could be a contaminant in argon matrix spectroscopic studies." @default.
- W2912397109 created "2019-02-21" @default.
- W2912397109 creator A5091168232 @default.
- W2912397109 date "2019-03-01" @default.
- W2912397109 modified "2023-09-27" @default.
- W2912397109 title "The <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si1.gif overflow=scroll><mml:mrow><mml:msubsup><mml:mrow><mml:mi mathvariant=normal>ArNH</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> noble gas molecule: Stability, vibrational frequencies, and spectroscopic constants" @default.
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- W2912397109 doi "https://doi.org/10.1016/j.jms.2019.02.001" @default.
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