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• W2912397232 abstract "Low-dimensional and geometrically frustrated spin-chain Sr3(Co/Ni)IrO6 compounds exhibit interesting physical phenomena due to the exotic anisotropy associated with the spin–orbit entangled Ir4+ state. Temperature dependent magnetic susceptibility of polycrystalline Sr3CoIrO6 characterizes the partially-disordered antiferromagnetic with TN1 ~ 90 K and the frozen state of this antiferromagnetic order below TN2 ~ 30 K. The fitting of χT versus T (K) data to the Ising model reveal that the intra-chain exchange interactions are ferromagnetic, whereas the inter-chain exchange correlations are antiferromagnetic. Field-induced alteration of the partially-disordered antiferromagnetic state in the temperature regime of TN1 ≤ T ≤ TN2 is responsible for the anomalous magnetic hysteresis loop. Further, a large value of isothermal magnetic-entropy change (ΔS M ~ 22 J kg−1K−1 for 7 T), absence of thermal hysteresis in magnetization and highly insulating nature consents Sr3CoIrO6 to be classified as a good magnetocaloric material for the low-temperature refrigeration." @default.
• W2912397232 created "2019-02-21" @default.
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• W2912397232 date "2019-02-13" @default.
• W2912397232 modified "2023-09-27" @default.
• W2912397232 title "Partially-disordered to frozen-state crossover induced magnetocaloric properties of the antiferromagnetic one-dimensional spin-chain Sr₃CoIrO₆" @default.
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• W2912397232 doi "https://doi.org/10.1088/2053-1591/ab03a4" @default.
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