FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912404791> ?p ?o ?g. }

• W2912404791 endingPage "2113" @default.
• W2912404791 startingPage "2106" @default.
• W2912404791 abstract "When a hydrophilic solute in water is suddenly turned into a hydrophobic species, for instance, by photoionization, a layer of hydrated water molecules forms around the solute on a time scale of a few picoseconds. We study the dynamic buildup of the hydration shell around a hydrophobic solute on the basis of a time-dependent dielectric continuum model. Information about the solvent is spectroscopically extracted from the relaxation dynamics of a test dipole inside a static Onsager sphere in the nonequilibrium solvent. The growth process is described phenomenologically within two approaches. First, we consider a time-dependent thickness of the hydration layer that grows from zero to a finite value over a finite time. Second, we assume a time-dependent complex permittivity within a finite layer region around the Onsager sphere. The layer is modeled as a continuous dielectric with a much slower fluctuation dynamics. We find a time-dependent frequency shift down to the blue of the resonant absorption of the dipole, together with a dynamically decreasing line width, as compared to bulk water. The blue shift reflects the work performed against the hydrogen-bonded network of the bulk solvent and is a directly measurable quantity. Our results are in agreement with an experiment on the hydrophobic solvation of iodine in water." @default.
• W2912404791 created "2019-02-21" @default.
• W2912404791 creator A5000707265 @default.
• W2912404791 creator A5018074660 @default.
• W2912404791 creator A5032450921 @default.
• W2912404791 creator A5035601749 @default.
• W2912404791 date "2019-02-07" @default.
• W2912404791 modified "2023-09-24" @default.
• W2912404791 title "Spectroscopic Signatures of the Dynamical Hydrophobic Solvation Shell Formation" @default.
• W2912404791 cites W1970201026 @default.
• W2912404791 cites W1992210899 @default.
• W2912404791 cites W1994146881 @default.
• W2912404791 cites W2015517515 @default.
• W2912404791 cites W2033147610 @default.
• W2912404791 cites W2045919136 @default.
• W2912404791 cites W2052737939 @default.
• W2912404791 cites W2052990847 @default.
• W2912404791 cites W2063201110 @default.
• W2912404791 cites W2081023938 @default.
• W2912404791 cites W2085266326 @default.
• W2912404791 cites W2085806783 @default.
• W2912404791 cites W2090594901 @default.
• W2912404791 cites W2094493821 @default.
• W2912404791 cites W2102086705 @default.
• W2912404791 cites W2102873314 @default.
• W2912404791 cites W2116716969 @default.
• W2912404791 cites W2117611274 @default.
• W2912404791 cites W2142706107 @default.
• W2912404791 cites W2153177791 @default.
• W2912404791 cites W2160462930 @default.
• W2912404791 cites W2326203395 @default.
• W2912404791 cites W2405355013 @default.
• W2912404791 cites W2566108937 @default.
• W2912404791 cites W2594816406 @default.
• W2912404791 cites W2606467362 @default.
• W2912404791 cites W2765776772 @default.
• W2912404791 cites W2996416466 @default.
• W2912404791 cites W3100474188 @default.
• W2912404791 cites W3101392086 @default.
• W2912404791 cites W3101873016 @default.
• W2912404791 cites W3102074653 @default.
• W2912404791 cites W3105886310 @default.
• W2912404791 cites W4256172841 @default.
• W2912404791 cites W2056013654 @default.
• W2912404791 doi "https://doi.org/10.1021/acs.jpcb.8b11885" @default.
• W2912404791 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30731041" @default.
• W2912404791 hasPublicationYear "2019" @default.
• W2912404791 type Work @default.
• W2912404791 sameAs 2912404791 @default.
• W2912404791 citedByCount "2" @default.
• W2912404791 countsByYear W29124047912022 @default.
• W2912404791 countsByYear W29124047912023 @default.
• W2912404791 crossrefType "journal-article" @default.
• W2912404791 hasAuthorship W2912404791A5000707265 @default.
• W2912404791 hasAuthorship W2912404791A5018074660 @default.
• W2912404791 hasAuthorship W2912404791A5032450921 @default.
• W2912404791 hasAuthorship W2912404791A5035601749 @default.
• W2912404791 hasBestOaLocation W29124047912 @default.
• W2912404791 hasConcept C119049451 @default.
• W2912404791 hasConcept C120665830 @default.
• W2912404791 hasConcept C121332964 @default.
• W2912404791 hasConcept C133386390 @default.
• W2912404791 hasConcept C147597530 @default.
• W2912404791 hasConcept C148093993 @default.
• W2912404791 hasConcept C149823470 @default.
• W2912404791 hasConcept C15744967 @default.
• W2912404791 hasConcept C159467904 @default.
• W2912404791 hasConcept C168651791 @default.
• W2912404791 hasConcept C173523689 @default.
• W2912404791 hasConcept C178790620 @default.
• W2912404791 hasConcept C185592680 @default.
• W2912404791 hasConcept C192562407 @default.
• W2912404791 hasConcept C2776029896 @default.
• W2912404791 hasConcept C2780471494 @default.
• W2912404791 hasConcept C41999313 @default.
• W2912404791 hasConcept C49040817 @default.
• W2912404791 hasConcept C520434653 @default.
• W2912404791 hasConcept C55005982 @default.
• W2912404791 hasConcept C59593255 @default.
• W2912404791 hasConcept C77805123 @default.
• W2912404791 hasConcept C97355855 @default.
• W2912404791 hasConceptScore W2912404791C119049451 @default.
• W2912404791 hasConceptScore W2912404791C120665830 @default.
• W2912404791 hasConceptScore W2912404791C121332964 @default.
• W2912404791 hasConceptScore W2912404791C133386390 @default.
• W2912404791 hasConceptScore W2912404791C147597530 @default.
• W2912404791 hasConceptScore W2912404791C148093993 @default.
• W2912404791 hasConceptScore W2912404791C149823470 @default.
• W2912404791 hasConceptScore W2912404791C15744967 @default.
• W2912404791 hasConceptScore W2912404791C159467904 @default.
• W2912404791 hasConceptScore W2912404791C168651791 @default.
• W2912404791 hasConceptScore W2912404791C173523689 @default.
• W2912404791 hasConceptScore W2912404791C178790620 @default.
• W2912404791 hasConceptScore W2912404791C185592680 @default.
• W2912404791 hasConceptScore W2912404791C192562407 @default.
• W2912404791 hasConceptScore W2912404791C2776029896 @default.
• W2912404791 hasConceptScore W2912404791C2780471494 @default.
• W2912404791 hasConceptScore W2912404791C41999313 @default.

• next