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- W2912420002 endingPage "4344" @default.
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- W2912420002 abstract "Abstract A chiral‐pool‐based synthesis of the platensimycin core was achieved using ( S )‐lactic acid as an inexpensive starting material. The cyclohexenone ring was closed in a Mukaiyama–Michael domino sequence, while the quaternary stereocenter was created by a highly stereoselective decarboxylative allylation. The spirobicyclic skeleton was constructed by a RCM reaction. A new silver(I)‐promoted cyclization reaction of Δ 6 ‐ and Δ 7 ‐α‐iodoketones was developed and applied for the pivotal carbon–carbon bond formation. The scope and limitations of this methodology are also presented." @default.
- W2912420002 created "2019-02-21" @default.
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- W2912420002 creator A5091075344 @default.
- W2912420002 date "2019-02-22" @default.
- W2912420002 modified "2023-10-15" @default.
- W2912420002 title "Enantioselective Synthesis of the Platensimycin Core by Silver(I)‐Promoted Cyclization of Δ<sup>6</sup>‐α‐Iodoketone" @default.
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- W2912420002 doi "https://doi.org/10.1002/chem.201900497" @default.
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