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- W2912441905 endingPage "3174" @default.
- W2912441905 startingPage "3167" @default.
- W2912441905 abstract "The construction of metallosupramolecular complexes toward interesting topological structures is a critical challenge for chemists. The fluctuation in the synthetic strategy, by keeping the same metal-ligand combination, has proved a very significant approach to construct metallosupramolecular architectures. Herein, by varying the reaction conditions four new DyIII-supramolecular complexes based on a flexible dihydrazone ligand H2L (H2L = bis(2-hydroxy-3-methoxybenzylidene)adipohydrazide) in cooperation with different anions and solvents having formulas [Dy4L4(μ2-N3)2](NO3)2·6CH3OH·2H2O (1), [Dy8L8(μ2-CH3OH)4]Cl8·6CH3OH·14H2O (2), [Dy12L12(μ2-OH)2(OH)6(CH3O)2](NO3)2·2CH3OH·14H2O (3), and [Dy12L12(μ2-OH)2(NO3)2(OH)3(CH3O)](NO3)4·22H2O (4), have been successfully synthesized and their crystal structures confirmed by single crystal X-ray diffraction studies. The structural study reveals that 1 and 2 have quadruple-stranded helicate and dual triple-stranded helicate supramolecular structures, respectively, while 3 and 4 display octahedron cagelike supramolecular structures. The magnetic studies reveal that complexes 1-3 exhibit slow magnetic relaxation behavior, while complex 4 displays a series of typical frequency-dependent relaxation signals at 0 Oe applied dc field which is a rare case in polynuclear 4f single-molecule magnet (SMM) family to date. Interestingly, the distinct magnetic dynamic behavior was noticed for nearly isoskeletal complexes 3 and 4, which can be attributed to the modification of the coordination environment around DyIII ions." @default.
- W2912441905 created "2019-02-21" @default.
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- W2912441905 date "2019-02-18" @default.
- W2912441905 modified "2023-10-10" @default.
- W2912441905 title "Construction of Metallosupramolecular Coordination Complexes: From Lanthanide Helicates to Octahedral Cages Showing Single-Molecule Magnet Behavior" @default.
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- W2912441905 cites W1710806325 @default.
- W2912441905 cites W1948282252 @default.
- W2912441905 cites W1965432692 @default.
- W2912441905 cites W1966870793 @default.
- W2912441905 cites W1968984308 @default.
- W2912441905 cites W1971321897 @default.
- W2912441905 cites W1978239898 @default.
- W2912441905 cites W1979303409 @default.
- W2912441905 cites W1984044268 @default.
- W2912441905 cites W1984867579 @default.
- W2912441905 cites W1991768771 @default.
- W2912441905 cites W1991860687 @default.
- W2912441905 cites W1992417778 @default.
- W2912441905 cites W1998023654 @default.
- W2912441905 cites W2010612077 @default.
- W2912441905 cites W2012093866 @default.
- W2912441905 cites W2012543885 @default.
- W2912441905 cites W2019519876 @default.
- W2912441905 cites W2040759172 @default.
- W2912441905 cites W2042642397 @default.
- W2912441905 cites W2047705453 @default.
- W2912441905 cites W2054125484 @default.
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- W2912441905 cites W2076355134 @default.
- W2912441905 cites W2092687179 @default.
- W2912441905 cites W2094264233 @default.
- W2912441905 cites W2109477907 @default.
- W2912441905 cites W2109795163 @default.
- W2912441905 cites W2133220369 @default.
- W2912441905 cites W2139668718 @default.
- W2912441905 cites W2145776938 @default.
- W2912441905 cites W2148409001 @default.
- W2912441905 cites W2157363131 @default.
- W2912441905 cites W2191919105 @default.
- W2912441905 cites W2204042680 @default.
- W2912441905 cites W2226014153 @default.
- W2912441905 cites W2253855183 @default.
- W2912441905 cites W2262193673 @default.
- W2912441905 cites W2314553643 @default.
- W2912441905 cites W2321928674 @default.
- W2912441905 cites W2325200105 @default.
- W2912441905 cites W2332402427 @default.
- W2912441905 cites W2332562407 @default.
- W2912441905 cites W2396821775 @default.
- W2912441905 cites W2401780237 @default.
- W2912441905 cites W2407024020 @default.
- W2912441905 cites W2504272741 @default.
- W2912441905 cites W2554471031 @default.
- W2912441905 cites W2565128051 @default.
- W2912441905 cites W2567099032 @default.
- W2912441905 cites W2590364906 @default.
- W2912441905 cites W2606769229 @default.
- W2912441905 cites W2609612189 @default.
- W2912441905 cites W2610531104 @default.
- W2912441905 cites W2618908670 @default.
- W2912441905 cites W2622992465 @default.
- W2912441905 cites W2740309892 @default.
- W2912441905 cites W2746821392 @default.
- W2912441905 cites W2769877684 @default.
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- W2912441905 cites W2793329345 @default.
- W2912441905 cites W2807107102 @default.
- W2912441905 cites W2883223600 @default.
- W2912441905 cites W2896968078 @default.
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- W2912441905 doi "https://doi.org/10.1021/acs.inorgchem.8b03249" @default.
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- W2912441905 hasPublicationYear "2019" @default.
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