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- W2912443316 abstract "Titanium silicalite (TS) and TiO 2 nanocomposites were prepared by mixing TS and TiO 2 with different ratios in ethanol. They were impregnated with 15 wt% Co loading to afford Co‐based catalysts. Fischer–Tropsch synthesis (FTS) performance of these TS–TiO 2 nanocomposite‐supported Co‐based catalysts was studied in a fixed‐bed tubular reactor. The results reveal that the Co/TS–TiO 2 catalysts have better catalytic performance than Co/TS or Co/TiO 2 each with a single support, showing the synergistic effect of the binary TS–TiO 2 support. Among the TS–TiO 2 nanocomposite‐supported Co‐based catalysts, Co/TS–TiO 2 ‐1 presents the highest activity. These catalysts were characterized using N 2 adsorption–desorption measurements, X‐ray diffraction, X‐ray photoelectron spectroscopy, H 2 temperature‐programmed reduction, H 2 temperature‐programmed desorption and transmission electron microscopy. It was found that the position of the active component has a significant effect on the catalytic activity. In the TS–TiO 2 nanocomposites, cobalt oxides located at the new pores developed between TS and TiO 2 can exhibit better catalytic activity. Also, a positive relationship is observed between Co dispersion and FTS catalytic performance for all catalysts. The catalytic activity is improved on increasing the dispersion of Co." @default.
- W2912443316 created "2019-02-21" @default.
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- W2912443316 date "2019-01-28" @default.
- W2912443316 modified "2023-10-16" @default.
- W2912443316 title "Effects of titanium silicalite and TiO<sub>2</sub> nanocomposites on supported Co-based catalysts for Fischer-Tropsch synthesis" @default.
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- W2912443316 doi "https://doi.org/10.1002/aoc.4640" @default.
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