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• W2912448260 endingPage "2593" @default.
• W2912448260 startingPage "2580" @default.
• W2912448260 abstract "A Mn(I)-based hybrid system (OrgD-|TiO2|-MnP) for photocatalytic CO2 reduction is designed to be a coassembly of Mn(4,4′-Y2-bpy)(CO)3Br (MnP; Y = CH2PO(OH)2) and (E)-3-[5-(4-(diphenylamino)phenyl)-2,2′-bithiophen-2′-yl]-2-cyanoacrylic acid (OrgD) on TiO2 semiconductor particles. The OrgD-|TiO2|-MnP hybrid reveals persistent photocatalytic behavior, giving high turnover numbers and good product selectivity (HCOO– versus CO). As a typical run, visible-light irradiation of the hybrid catalyst in the presence of 0.1 M electron donor (ED) and 0.001 M LiClO4 persistently produced HCOO– with a >99% selectivity accompanied by a trace amount of CO; the turnover number (TONformate) reached ∼250 after 23 h of irradiation. The product selectivity (HCOO–/CO) was found to be controlled by changing the loading amount of MnP on the TiO2 surface. In situ FTIR analysis of the hybrid during photocatalysis revealed that, at low Mn concentration, the Mn–H monomeric mechanism associated with HCOO– formation is dominant, whereas at high Mn concentration, CO is formed via a Mn–Mn dimer mechanism." @default.
• W2912448260 created "2019-02-21" @default.
• W2912448260 creator A5011606548 @default.
• W2912448260 creator A5021509376 @default.
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• W2912448260 creator A5042002197 @default.
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• W2912448260 creator A5088524416 @default.
• W2912448260 creator A5089504310 @default.
• W2912448260 date "2019-01-31" @default.
• W2912448260 modified "2023-10-18" @default.
• W2912448260 title "Highly Selective and Durable Photochemical CO₂ Reduction by Molecular Mn(I) Catalyst Fixed on a Particular Dye-Sensitized TiO₂ Platform" @default.
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• W2912448260 doi "https://doi.org/10.1021/acscatal.8b03816" @default.

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