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- W2912448283 abstract "An unprecedented Pd-catalyzed alkyne insertion/C-H activation/intramolecular [4 + 2] carboannulation of alkenes has been reported. In this transformation, the C-H activation was triggered by an in situ generated alkenylpalladium species via the Pd-catalyzed cross-coupling reaction of aryl iodides and alkynes. Subsequently, the resulting five-membered C, C-palladacycle intermediates were added across the alkenes, providing a unique approach to access diversified polycyclics in good efficiency. Two new rings and three C-C bonds were formed in one pot." @default.
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- W2912448283 date "2019-01-29" @default.
- W2912448283 modified "2023-10-09" @default.
- W2912448283 title "Pd-Catalyzed Alkyne Insertion/C–H Activation/[4 + 2] Carboannulation of Alkenes to the Synthesis of Polycyclics" @default.
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- W2912448283 doi "https://doi.org/10.1021/acs.orglett.8b03884" @default.
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