Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912463242> ?p ?o ?g. }
- W2912463242 abstract "The significant issues with alkali metal batteries arise from their poor electrochemical properties and safety problems, limiting their applications. Herein, TiO2 nanoparticles embedded into N-doped porous carbon truncated ocatahedra (TiO2 ⊂NPCTO) are engineered as a cathode material with different metal anodes, including solid Na or K and liquid Na-K alloy. Electrochemical performance and kinetics are systematically analyzed, with the aim to determine detailed electrochemistry. By using a galvanostatic intermittent titration technique, TiO2 ⊂NPCTO/NaK shows faster diffusion of metal ions in insertion and extraction processes than that of Na-ions and K-ions in solid Na and K. The lower reaction resistance of liquid Na-K alloy electrode is also examined. The higher b-value of TiO2 ⊂NPCTO/NaK confirms that the reaction kinetics are promoted by the surface-induced capacitive behavior, favorable for high rate performance. This superiority highly pertains to the distinct liquid-liquid junction between the electrolyte and electrode, and the prohibition of metal dendrite growth, substantiated by symmetric cell testing, which provides a robust and homogeneous interface more stable than the traditional solid-liquid one. Hence, the liquid Na-K alloy-based battery exhibits to better cyclablity with higher capacity, rate capability, and initial coulombic efficiency than solid Na and K batteries." @default.
- W2912463242 created "2019-02-21" @default.
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- W2912463242 date "2019-02-10" @default.
- W2912463242 modified "2023-10-18" @default.
- W2912463242 title "New Insights into the Electrochemistry Superiority of Liquid Na–K Alloy in Metal Batteries" @default.
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- W2912463242 doi "https://doi.org/10.1002/smll.201804916" @default.
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