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- W2912485745 abstract "Sulfur-centered phenyl, n-butyl, p-tolyl, and benzyl sulfoniums and sulfides were tested as organic structure-directing agents (SDAs) for the synthesis of crystalline microporous aluminophosphates (AlPOs) over various ranges of gel compositions, hydrothermal treatment temperatures, and crystallization times. Among the investigated compounds, triphenylsulfonium gave single-phase products of ATS-type AlPO and silicoaluminophosphate. Other sulfoniums yielded only non-porous, dense crystalline AlPOs. On the other hand, diaryl sulfides gave a tiny amount of AFI-type AlPO amid tridymite and amorphous phases. Based on the results, it was found to be reasonable that weakly basic sulfide could hardly act as a zeotype SDA due to the low protonation to sulfonium at the present synthesis pH." @default.
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- W2912485745 date "2019-05-01" @default.
- W2912485745 modified "2023-09-25" @default.
- W2912485745 title "Sulfonium-based organic structure-directing agents for microporous aluminophosphate synthesis" @default.
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- W2912485745 doi "https://doi.org/10.1016/j.micromeso.2019.01.048" @default.
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