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- W2912488671 abstract "A novel type of oxacalix[2]arene[2]triazine-based organocatalysts for asymmetric Michael reactions are reported for the first time. Chiral subunits were attached to the heteroatom-bridged calixaromatic platform by a reaction of (R)- and (S)-1-aminotetraline with tetraoxacalix[2]arene[2]triazine in both enantiomeric forms. To evaluate the catalytic efficiency of the novel organocatalysts, isobutyraldehyde reacted with various substituted and unsubstituted aromatic trans-β-nitrostyrenes in tetrahydrofuran (THF), leading to Michael adducts in excellent yields and enantioselectivites (up to 97% yield and 99% ee)." @default.
- W2912488671 created "2019-02-21" @default.
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- W2912488671 creator A5049967254 @default.
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- W2912488671 date "2019-01-31" @default.
- W2912488671 modified "2023-09-26" @default.
- W2912488671 title "Design, synthesis and application of chiral tetraoxacalix[2]arene[2]triazine‐based organocatalysts in asymmetric Michael addition reactions" @default.
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- W2912488671 doi "https://doi.org/10.1002/chir.23055" @default.
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