Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912502021> ?p ?o ?g. }
- W2912502021 endingPage "862" @default.
- W2912502021 startingPage "852" @default.
- W2912502021 abstract "Studies on the deactivation mechanism of the reaction of N,N-dialkylamides with TMDS catalyzed by Vaska’s complex, IrCl(CO)(PPh3)2 (1a), triggered the discovery of highly active Ir-PPh3 catalysts: photochemically activated 1a and thermally activated IrCl(PPh3)3 (8). Both catalysts showed excellent activity toward the selective conversion of a variety of N,N-dialkyl-, N-alkyl-N-aryl-, and N,N-diarylamides to the corresponding enamines with low catalyst loadings. The 14-electron species “ClIr(PPh3)2”, which is stabilized by solvents or reactants in the actual catalytic reactions, could be involved in the catalysis, which produces “HIr(PPh3)2” and “SiIr(PPh3)2” (Si = Me2HSiOMe2Si−) species in the catalytic cycle. An in situ generation method for the “ClIrL2” species was established by simply mixing [IrCl(η4-COD)]2 with PPh3 or other phosphorus ligands, which realized the facile large-scale syntheses of enamines." @default.
- W2912502021 created "2019-02-21" @default.
- W2912502021 creator A5003001704 @default.
- W2912502021 creator A5004628028 @default.
- W2912502021 creator A5024622148 @default.
- W2912502021 creator A5066949888 @default.
- W2912502021 creator A5079315041 @default.
- W2912502021 date "2019-02-05" @default.
- W2912502021 modified "2023-10-16" @default.
- W2912502021 title "Iridium-PPh3 Catalysts for Conversion of Amides to Enamines" @default.
- W2912502021 cites W125452486 @default.
- W2912502021 cites W1492132946 @default.
- W2912502021 cites W1501622035 @default.
- W2912502021 cites W1509179601 @default.
- W2912502021 cites W1596882163 @default.
- W2912502021 cites W1599347560 @default.
- W2912502021 cites W1772948919 @default.
- W2912502021 cites W1966648243 @default.
- W2912502021 cites W1971758201 @default.
- W2912502021 cites W1978014013 @default.
- W2912502021 cites W1981373145 @default.
- W2912502021 cites W1982998499 @default.
- W2912502021 cites W1991310001 @default.
- W2912502021 cites W1996915121 @default.
- W2912502021 cites W2002156127 @default.
- W2912502021 cites W2007490298 @default.
- W2912502021 cites W2008086922 @default.
- W2912502021 cites W2018085360 @default.
- W2912502021 cites W2021662556 @default.
- W2912502021 cites W2025909608 @default.
- W2912502021 cites W2027193718 @default.
- W2912502021 cites W2028813307 @default.
- W2912502021 cites W2030289686 @default.
- W2912502021 cites W2033884872 @default.
- W2912502021 cites W2039931669 @default.
- W2912502021 cites W2040270294 @default.
- W2912502021 cites W2054481520 @default.
- W2912502021 cites W2056907852 @default.
- W2912502021 cites W2060083850 @default.
- W2912502021 cites W2063032427 @default.
- W2912502021 cites W2071097677 @default.
- W2912502021 cites W2071583288 @default.
- W2912502021 cites W2072094726 @default.
- W2912502021 cites W2072259571 @default.
- W2912502021 cites W2073888779 @default.
- W2912502021 cites W2075229309 @default.
- W2912502021 cites W2076300705 @default.
- W2912502021 cites W2091163797 @default.
- W2912502021 cites W2101687918 @default.
- W2912502021 cites W2103437347 @default.
- W2912502021 cites W2115523163 @default.
- W2912502021 cites W2122405547 @default.
- W2912502021 cites W2130266205 @default.
- W2912502021 cites W2135106729 @default.
- W2912502021 cites W2138514665 @default.
- W2912502021 cites W2179356784 @default.
- W2912502021 cites W2312473876 @default.
- W2912502021 cites W2312674207 @default.
- W2912502021 cites W2317067574 @default.
- W2912502021 cites W2317968933 @default.
- W2912502021 cites W2324160233 @default.
- W2912502021 cites W2325203204 @default.
- W2912502021 cites W2331357339 @default.
- W2912502021 cites W2339003249 @default.
- W2912502021 cites W2417388061 @default.
- W2912502021 cites W2516356348 @default.
- W2912502021 cites W2590471115 @default.
- W2912502021 cites W2599243505 @default.
- W2912502021 cites W2607420875 @default.
- W2912502021 cites W2614050782 @default.
- W2912502021 cites W2618399258 @default.
- W2912502021 cites W2622502211 @default.
- W2912502021 cites W2940954349 @default.
- W2912502021 cites W2949200478 @default.
- W2912502021 cites W2949513481 @default.
- W2912502021 cites W2949901835 @default.
- W2912502021 cites W3005195422 @default.
- W2912502021 cites W3138695322 @default.
- W2912502021 cites W1489176797 @default.
- W2912502021 doi "https://doi.org/10.1021/acs.organomet.8b00835" @default.
- W2912502021 hasPublicationYear "2019" @default.
- W2912502021 type Work @default.
- W2912502021 sameAs 2912502021 @default.
- W2912502021 citedByCount "23" @default.
- W2912502021 countsByYear W29125020212019 @default.
- W2912502021 countsByYear W29125020212020 @default.
- W2912502021 countsByYear W29125020212021 @default.
- W2912502021 countsByYear W29125020212022 @default.
- W2912502021 countsByYear W29125020212023 @default.
- W2912502021 crossrefType "journal-article" @default.
- W2912502021 hasAuthorship W2912502021A5003001704 @default.
- W2912502021 hasAuthorship W2912502021A5004628028 @default.
- W2912502021 hasAuthorship W2912502021A5024622148 @default.
- W2912502021 hasAuthorship W2912502021A5066949888 @default.
- W2912502021 hasAuthorship W2912502021A5079315041 @default.
- W2912502021 hasConcept C155647269 @default.
- W2912502021 hasConcept C161790260 @default.
- W2912502021 hasConcept C178790620 @default.