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• W2912532698 abstract "Purpose The purpose of this paper is to study the electrochemical behavior of Sn electrode in Na 2 B 2 O 7 solutions in the absence and presence of NaNO 3 as a pitting corrosion agent. Design/methodology/approach The electrochemical behavior of Sn electrode was studied by using cyclic voltammetry and potentiodynamic polarization measurements and complemented with scanning electron microscopy examinations. Findings This paper shows that in the absence of NO 3 − ions, the anodic polarization of Sn electrode exhibits active/passive transition. Addition of various concentrations of NO 3 − anions to the borate solution enhances active anodic dissolution and tends to break down the passive oxide film at a certain pitting potential. The pitting potential, and hence the pitting corrosion resistance, decreases with increasing NO 3 -ion concentration and temperature but increases with scan rate and repetitive cycling. Addition of CrO 4 2− , WO 4 2− or MoO 4 2− oxyanions to the borate nitrate solution inhibits the pitting corrosion of Sn. Originality/value This is the first study that shows the effect of NO 3 − ion as a pitting corrosion agent." @default.
• W2912532698 created "2019-02-21" @default.
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• W2912532698 date "2019-05-07" @default.
• W2912532698 modified "2023-09-26" @default.
• W2912532698 title "Electrochemical studies on pitting corrosion of tin in sodium borate solutions containing nitrate ions" @default.
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• W2912532698 doi "https://doi.org/10.1108/acmm-07-2018-1972" @default.
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