Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912541934> ?p ?o ?g. }
- W2912541934 endingPage "3236" @default.
- W2912541934 startingPage "3227" @default.
- W2912541934 abstract "A Zr metal–organic framework (MOF) 1-CoCl3 has been synthesized by solvothermal reaction of ZrCl4 with a carboxylic acid-functionalized CoIII-PNNNP pincer complex H4(L-CoCl3) ([L-CoCl3]4– = [(2,6-(NHPAr2)2C6H3)CoCl3]4–, Ar = p-C6H4CO2–). The structure of 1-CoCl3 has been determined by X-ray powder diffraction and exhibits a csq topology that differs from previously reported ftw-net Zr MOFs assembled from related PdII- and PtII-PNNNP pincer complexes. The Co-PNNNP pincer species readily demetallate upon reduction of CoIII to CoII, allowing for transmetalation with late second and third row transition metals in both the homogeneous complex and 1-CoCl3. Reaction of 1-CoCl3 with [Rh(nbd)Cl]2 (nbd = 2,5-nobornadiene) results in complete Rh/Co metal exchange at the supported diphosphine pincer complexes to generate 1-RhCl, which has been inaccessible by direct solvothermal synthesis. Treating 1-CoCl3 with PtCl2(SMe2)2 in the presence of the mild reductant NEt3 resulted in nearly complete Co substitution by Pt. In addition, a mixed metal pincer MOF, 1-PtRh, was generated by sequential substitution of Co with Pt followed by Rh." @default.
- W2912541934 created "2019-02-21" @default.
- W2912541934 creator A5004494409 @default.
- W2912541934 creator A5008505182 @default.
- W2912541934 creator A5039639110 @default.
- W2912541934 creator A5048380860 @default.
- W2912541934 creator A5065870564 @default.
- W2912541934 creator A5071784856 @default.
- W2912541934 date "2019-02-14" @default.
- W2912541934 modified "2023-10-06" @default.
- W2912541934 title "Postsynthetic Metal Exchange in a Metal–Organic Framework Assembled from Co(III) Diphosphine Pincer Complexes" @default.
- W2912541934 cites W1966910457 @default.
- W2912541934 cites W1979287992 @default.
- W2912541934 cites W1979628906 @default.
- W2912541934 cites W1983772770 @default.
- W2912541934 cites W1993274520 @default.
- W2912541934 cites W2003943583 @default.
- W2912541934 cites W2007082361 @default.
- W2912541934 cites W2013651121 @default.
- W2912541934 cites W2016029216 @default.
- W2912541934 cites W2020102842 @default.
- W2912541934 cites W2025831662 @default.
- W2912541934 cites W2026815967 @default.
- W2912541934 cites W2039851531 @default.
- W2912541934 cites W2065948329 @default.
- W2912541934 cites W2067505217 @default.
- W2912541934 cites W2075287035 @default.
- W2912541934 cites W2075320657 @default.
- W2912541934 cites W2080572116 @default.
- W2912541934 cites W2084115826 @default.
- W2912541934 cites W2101268642 @default.
- W2912541934 cites W2103938576 @default.
- W2912541934 cites W2104613429 @default.
- W2912541934 cites W2105761150 @default.
- W2912541934 cites W2139544684 @default.
- W2912541934 cites W2141939342 @default.
- W2912541934 cites W2153808550 @default.
- W2912541934 cites W2155579681 @default.
- W2912541934 cites W2164723090 @default.
- W2912541934 cites W2254066232 @default.
- W2912541934 cites W2260946417 @default.
- W2912541934 cites W2276886307 @default.
- W2912541934 cites W2290495632 @default.
- W2912541934 cites W2313650448 @default.
- W2912541934 cites W2316682395 @default.
- W2912541934 cites W2318759534 @default.
- W2912541934 cites W2322357129 @default.
- W2912541934 cites W2327142354 @default.
- W2912541934 cites W2333875011 @default.
- W2912541934 cites W2412679450 @default.
- W2912541934 cites W2466547545 @default.
- W2912541934 cites W2481959494 @default.
- W2912541934 cites W2508759636 @default.
- W2912541934 cites W2509535659 @default.
- W2912541934 cites W2517747609 @default.
- W2912541934 cites W2536054323 @default.
- W2912541934 cites W2537805641 @default.
- W2912541934 cites W2578309348 @default.
- W2912541934 cites W2586554840 @default.
- W2912541934 cites W2592521434 @default.
- W2912541934 cites W2597269254 @default.
- W2912541934 cites W2604619220 @default.
- W2912541934 cites W2605360034 @default.
- W2912541934 cites W2607848054 @default.
- W2912541934 cites W2617135749 @default.
- W2912541934 cites W2652823536 @default.
- W2912541934 cites W2744528294 @default.
- W2912541934 cites W2758856374 @default.
- W2912541934 cites W2760345354 @default.
- W2912541934 cites W2760777285 @default.
- W2912541934 cites W2765884406 @default.
- W2912541934 cites W2766897876 @default.
- W2912541934 cites W2768081419 @default.
- W2912541934 cites W2775180995 @default.
- W2912541934 cites W2779554386 @default.
- W2912541934 cites W2782602425 @default.
- W2912541934 cites W2783932357 @default.
- W2912541934 cites W2784103179 @default.
- W2912541934 cites W2788908336 @default.
- W2912541934 cites W2790795631 @default.
- W2912541934 cites W2794316136 @default.
- W2912541934 cites W2795132984 @default.
- W2912541934 cites W2801333910 @default.
- W2912541934 cites W2802636391 @default.
- W2912541934 cites W2893476926 @default.
- W2912541934 cites W2900661789 @default.
- W2912541934 cites W2904767477 @default.
- W2912541934 doi "https://doi.org/10.1021/acs.inorgchem.8b03318" @default.
- W2912541934 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30762343" @default.
- W2912541934 hasPublicationYear "2019" @default.
- W2912541934 type Work @default.
- W2912541934 sameAs 2912541934 @default.
- W2912541934 citedByCount "21" @default.
- W2912541934 countsByYear W29125419342019 @default.
- W2912541934 countsByYear W29125419342020 @default.
- W2912541934 countsByYear W29125419342021 @default.
- W2912541934 countsByYear W29125419342022 @default.
- W2912541934 countsByYear W29125419342023 @default.