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- W2912542384 endingPage "1955" @default.
- W2912542384 startingPage "1947" @default.
- W2912542384 abstract "ABSTRACT As one of the emerging techniques for preparing discrete oligomers, the photo‐RAFT single unit monomer insertion (SUMI) process has shown its uniqueness and superiority in the control of both monomer sequence and stereochemistry. However, current precision polymer synthesis techniques are still burdened by the scalability challenges, such as low reaction yields, small product quantities, and long production times. Herein, we successfully established a practical protocol to address scalability problems in the photo‐RAFT SUMI processes. A series of discrete oligomers containing up to five monomer units were synthesized in batch and flow reactors by sequential and alternating SUMI of two monomers into a trithiocarbonate RAFT agent under mild reaction conditions and purified by automated flash chromatography. This protocol offers the process with large quantity (grams scale), excellent isolated yields (82%–95% for each step and 59% for five iterations), and short production time (several days for a pentamer). © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1947–1955" @default.
- W2912542384 created "2019-02-21" @default.
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- W2912542384 creator A5018120068 @default.
- W2912542384 creator A5041558999 @default.
- W2912542384 creator A5047900689 @default.
- W2912542384 date "2019-01-30" @default.
- W2912542384 modified "2023-10-12" @default.
- W2912542384 title "Upscaling single unit monomer insertion to synthesize discrete oligomers" @default.
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- W2912542384 doi "https://doi.org/10.1002/pola.29330" @default.
- W2912542384 hasPublicationYear "2019" @default.
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