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• W2912572031 endingPage "4148" @default.
• W2912572031 startingPage "4143" @default.
• W2912572031 abstract "Abstract Inspired by the recent interest in fast ionic conducting solids for electrolytes, the ionic conductivity of a novel ionic conductor Na 1+ x Ti 2− x Ga x (PS 4 ) 3 has been investigated. Using X‐ray diffraction and impedance spectroscopy the sodium ionic conductivity in this compound was demonstrated, in which bond valence sum analysis suggests a tunnel diffusion for Na + . Substitution with Ga 3+ leads to an increasing Na + content, an expansion of the lattice and an increasing conductivity with increasing x in Na 1+ x Ti 2− x Ga x (PS 4 ) 3 . Given the relation to the NASICON family, upon replacement of the phosphate by a thiophosphate group, a rich structural chemistry can be expected in this class of materials. This work demonstrates the potential for making NaTi 2 (PS 4 ) 3 an ideal system to study structure‐property relationships in ionic conductors." @default.
• W2912572031 created "2019-02-21" @default.
• W2912572031 creator A5000894382 @default.
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• W2912572031 date "2019-02-18" @default.
• W2912572031 modified "2023-10-10" @default.
• W2912572031 title "Ionic Conductivity of the NASICON‐Related Thiophosphate Na_1+<i>x</i>Ti_2−<i>x</i>Ga_<i>x</i>(PS₄)₃" @default.
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• W2912572031 doi "https://doi.org/10.1002/chem.201805569" @default.
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• W2912572031 hasPublicationYear "2019" @default.
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