FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912572234> ?p ?o ?g. }

• W2912572234 endingPage "2730" @default.
• W2912572234 startingPage "2721" @default.
• W2912572234 abstract "Here we present a detailed kinetic study of the multisite proton-coupled electron transfer (MS-PCET) activations of aryl ketones using a variety of Brønsted acids and excited-state Ir(III)-based electron donors. A simple method is described for simultaneously extracting both the hydrogen-bonding equilibrium constants and the rate constants for the PCET event from deconvolution of the luminescence quenching data. These experiments confirm that these activations occur in a concerted fashion, wherein the proton and electron are transferred to the ketone substrate in a single elementary step. The rates constants for the PCET events were linearly correlated with their driving forces over a range of nearly 19 kcal/mol. However, the slope of the rate–driving force relationship deviated significantly from expectations based on Marcus theory. A rationalization for this observation is proposed based on the principle of non-perfect synchronization, wherein factors that serve to stabilize the product are only partially realized at the transition state. A discussion of the relevance of these findings to the applications of MS-PCET in organic synthesis is also presented." @default.
• W2912572234 created "2019-02-21" @default.
• W2912572234 creator A5004919546 @default.
• W2912572234 creator A5034006875 @default.
• W2912572234 date "2019-01-21" @default.
• W2912572234 modified "2023-09-27" @default.
• W2912572234 title "Rate–Driving Force Relationships in the Multisite Proton-Coupled Electron Transfer Activation of Ketones" @default.
• W2912572234 cites W107423236 @default.
• W2912572234 cites W1157446105 @default.
• W2912572234 cites W1968963012 @default.
• W2912572234 cites W1974404541 @default.
• W2912572234 cites W1975240662 @default.
• W2912572234 cites W1976205221 @default.
• W2912572234 cites W1981989568 @default.
• W2912572234 cites W1983731372 @default.
• W2912572234 cites W1986530495 @default.
• W2912572234 cites W1986670180 @default.
• W2912572234 cites W1987097727 @default.
• W2912572234 cites W1992485951 @default.
• W2912572234 cites W1994385611 @default.
• W2912572234 cites W1996408951 @default.
• W2912572234 cites W1998346292 @default.
• W2912572234 cites W1999923041 @default.
• W2912572234 cites W2000137428 @default.
• W2912572234 cites W2001270915 @default.
• W2912572234 cites W2001823292 @default.
• W2912572234 cites W2007128428 @default.
• W2912572234 cites W2007824877 @default.
• W2912572234 cites W2008570730 @default.
• W2912572234 cites W2019692171 @default.
• W2912572234 cites W2023649594 @default.
• W2912572234 cites W2029615583 @default.
• W2912572234 cites W2031766770 @default.
• W2912572234 cites W2031904472 @default.
• W2912572234 cites W2038312285 @default.
• W2912572234 cites W2041930594 @default.
• W2912572234 cites W2042443749 @default.
• W2912572234 cites W2044848524 @default.
• W2912572234 cites W2048173493 @default.
• W2912572234 cites W2049822774 @default.
• W2912572234 cites W2056735473 @default.
• W2912572234 cites W2063790095 @default.
• W2912572234 cites W2063800957 @default.
• W2912572234 cites W2070127123 @default.
• W2912572234 cites W2073619962 @default.
• W2912572234 cites W2074858575 @default.
• W2912572234 cites W2075552235 @default.
• W2912572234 cites W2078887629 @default.
• W2912572234 cites W2082986749 @default.
• W2912572234 cites W2127737840 @default.
• W2912572234 cites W2144978325 @default.
• W2912572234 cites W2156408437 @default.
• W2912572234 cites W2183552841 @default.
• W2912572234 cites W2272976663 @default.
• W2912572234 cites W2312208708 @default.
• W2912572234 cites W2316888293 @default.
• W2912572234 cites W2322631918 @default.
• W2912572234 cites W2345777662 @default.
• W2912572234 cites W2345800965 @default.
• W2912572234 cites W2488628364 @default.
• W2912572234 cites W2504256884 @default.
• W2912572234 cites W2515171599 @default.
• W2912572234 cites W2530596944 @default.
• W2912572234 cites W2588298887 @default.
• W2912572234 cites W2602573681 @default.
• W2912572234 cites W2729104732 @default.
• W2912572234 cites W2765349976 @default.
• W2912572234 cites W2767295563 @default.
• W2912572234 cites W2779028904 @default.
• W2912572234 cites W2788466870 @default.
• W2912572234 cites W2884448902 @default.
• W2912572234 cites W2897378427 @default.
• W2912572234 cites W2899266997 @default.
• W2912572234 cites W2951327262 @default.
• W2912572234 cites W2951706303 @default.
• W2912572234 cites W3005352396 @default.
• W2912572234 cites W4211091797 @default.
• W2912572234 doi "https://doi.org/10.1021/jacs.8b13451" @default.
• W2912572234 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6508549" @default.
• W2912572234 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30665301" @default.
• W2912572234 hasPublicationYear "2019" @default.
• W2912572234 type Work @default.
• W2912572234 sameAs 2912572234 @default.
• W2912572234 citedByCount "50" @default.
• W2912572234 countsByYear W29125722342019 @default.
• W2912572234 countsByYear W29125722342020 @default.
• W2912572234 countsByYear W29125722342021 @default.
• W2912572234 countsByYear W29125722342022 @default.
• W2912572234 countsByYear W29125722342023 @default.
• W2912572234 crossrefType "journal-article" @default.
• W2912572234 hasAuthorship W2912572234A5004919546 @default.
• W2912572234 hasAuthorship W2912572234A5034006875 @default.
• W2912572234 hasBestOaLocation W29125722342 @default.
• W2912572234 hasConcept C110010208 @default.
• W2912572234 hasConcept C121332964 @default.
• W2912572234 hasConcept C121745418 @default.
• W2912572234 hasConcept C123669783 @default.
• W2912572234 hasConcept C147597530 @default.

• next