FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2912591709> ?p ?o ?g. }

• W2912591709 endingPage "1519" @default.
• W2912591709 startingPage "1512" @default.
• W2912591709 abstract "Supported ultrasmall noble metal nanocluster-based (UNMN-based) catalysts are one of the most important classes of solid materials for heterogeneous catalysis. In this work, we present a novel strategy for the controlled synthesis of ligand-free UNMN nanocatalysts based on in situ reduction of a palladium-based (Pd-based) metal-organic cage (MOC) confined within monosized, thiol-modified mesoporous silica nanoparticle (MSN) supports. By taking advantage of the high mutual solubility of MOCs and MSNs in DMSO and the strong interactions between the thiol-modified MSN pore wall and MOC surface, a good dispersion of MOC molecules was achieved throughout the MSN support. The close correspondence of the MSN pore diameter (ca. 5.0 nm) with the diameter of the MOC (ca. 4.0 nm) confines MOC packing to approximately a monolayer. Based on this spatial constraint and electrostatic binding of the MOC to the thiol-modified MSN pore surface, in situ MOC reduction followed by metal atom diffusion, coalescence, and anchoring on the active sites resulted in ligand-free Pd-based UNMNs of approximately 0.9 ± 0.2 nm in diameter decorating the MSN pore surfaces. Control experiments of the reduction of a conventional palladium source or the reduction of free, unconstrained cages in solution under the same conditions only produced large metal nanocrystals (NP, >2 nm), confirming the importance of confined reduction to achieve a highly catalytically active surface. In light of this strategy, two catalytic experiments including the reaction of 4-nitrophenol to 4-aminophenol and the Suzuki C-C coupling reaction show superior catalytic activity of the engineered MSN-supported UNMN nanocatalysts compared to their free form and state of the art commercial catalysts. We believe that our new strategy will open new avenues for artificially designed UNMN-inspired nanoarchitectures for wide applications." @default.
• W2912591709 created "2019-02-21" @default.
• W2912591709 creator A5006212005 @default.
• W2912591709 creator A5040430480 @default.
• W2912591709 creator A5055888032 @default.
• W2912591709 creator A5067601210 @default.
• W2912591709 creator A5075584064 @default.
• W2912591709 date "2019-02-04" @default.
• W2912591709 modified "2023-10-16" @default.
• W2912591709 title "Conversion of Metal–Organic Cage to Ligand-Free Ultrasmall Noble Metal Nanocluster Catalysts Confined within Mesoporous Silica Nanoparticle Supports" @default.
• W2912591709 cites W1811297454 @default.
• W2912591709 cites W1920285291 @default.
• W2912591709 cites W1971775718 @default.
• W2912591709 cites W1975192546 @default.
• W2912591709 cites W1979584177 @default.
• W2912591709 cites W1984646865 @default.
• W2912591709 cites W1992097701 @default.
• W2912591709 cites W1999560170 @default.
• W2912591709 cites W2000096824 @default.
• W2912591709 cites W2010311710 @default.
• W2912591709 cites W2013923256 @default.
• W2912591709 cites W2033270806 @default.
• W2912591709 cites W2050526139 @default.
• W2912591709 cites W2050564345 @default.
• W2912591709 cites W2088659153 @default.
• W2912591709 cites W2094642979 @default.
• W2912591709 cites W2095146078 @default.
• W2912591709 cites W2098825964 @default.
• W2912591709 cites W2099563945 @default.
• W2912591709 cites W2101671931 @default.
• W2912591709 cites W2101996575 @default.
• W2912591709 cites W2102830904 @default.
• W2912591709 cites W2120896748 @default.
• W2912591709 cites W2145121636 @default.
• W2912591709 cites W2155637231 @default.
• W2912591709 cites W2159203122 @default.
• W2912591709 cites W2160086456 @default.
• W2912591709 cites W2162256094 @default.
• W2912591709 cites W2162610957 @default.
• W2912591709 cites W2171154695 @default.
• W2912591709 cites W2295082037 @default.
• W2912591709 cites W2308720184 @default.
• W2912591709 cites W2315219461 @default.
• W2912591709 cites W2317296864 @default.
• W2912591709 cites W2319295441 @default.
• W2912591709 cites W2394672153 @default.
• W2912591709 cites W2414108457 @default.
• W2912591709 cites W2464367759 @default.
• W2912591709 cites W2465077322 @default.
• W2912591709 cites W2515286324 @default.
• W2912591709 cites W2552967902 @default.
• W2912591709 cites W2565825795 @default.
• W2912591709 cites W2734756276 @default.
• W2912591709 doi "https://doi.org/10.1021/acs.nanolett.8b04121" @default.
• W2912591709 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30716276" @default.
• W2912591709 hasPublicationYear "2019" @default.
• W2912591709 type Work @default.
• W2912591709 sameAs 2912591709 @default.
• W2912591709 citedByCount "32" @default.
• W2912591709 countsByYear W29125917092019 @default.
• W2912591709 countsByYear W29125917092020 @default.
• W2912591709 countsByYear W29125917092021 @default.
• W2912591709 countsByYear W29125917092022 @default.
• W2912591709 countsByYear W29125917092023 @default.
• W2912591709 crossrefType "journal-article" @default.
• W2912591709 hasAuthorship W2912591709A5006212005 @default.
• W2912591709 hasAuthorship W2912591709A5040430480 @default.
• W2912591709 hasAuthorship W2912591709A5055888032 @default.
• W2912591709 hasAuthorship W2912591709A5067601210 @default.
• W2912591709 hasAuthorship W2912591709A5075584064 @default.
• W2912591709 hasConcept C116569031 @default.
• W2912591709 hasConcept C127413603 @default.
• W2912591709 hasConcept C13205572 @default.
• W2912591709 hasConcept C155672457 @default.
• W2912591709 hasConcept C161790260 @default.
• W2912591709 hasConcept C170493617 @default.
• W2912591709 hasConcept C171250308 @default.
• W2912591709 hasConcept C178790620 @default.
• W2912591709 hasConcept C185592680 @default.
• W2912591709 hasConcept C192562407 @default.
• W2912591709 hasConcept C2775871042 @default.
• W2912591709 hasConcept C2777496208 @default.
• W2912591709 hasConcept C42360764 @default.
• W2912591709 hasConcept C45083100 @default.
• W2912591709 hasConcept C502130503 @default.
• W2912591709 hasConcept C544153396 @default.
• W2912591709 hasConcept C55493867 @default.
• W2912591709 hasConcept C82776694 @default.
• W2912591709 hasConceptScore W2912591709C116569031 @default.
• W2912591709 hasConceptScore W2912591709C127413603 @default.
• W2912591709 hasConceptScore W2912591709C13205572 @default.
• W2912591709 hasConceptScore W2912591709C155672457 @default.
• W2912591709 hasConceptScore W2912591709C161790260 @default.
• W2912591709 hasConceptScore W2912591709C170493617 @default.
• W2912591709 hasConceptScore W2912591709C171250308 @default.
• W2912591709 hasConceptScore W2912591709C178790620 @default.
• W2912591709 hasConceptScore W2912591709C185592680 @default.
• W2912591709 hasConceptScore W2912591709C192562407 @default.

• next