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- W2912595994 abstract "This chapter presents several new indole syntheses from pyrroles, as deserve to be revealed as being promising for future applications. Queguiner and coworkers found a simple benzannulation of methylpyrrole-2,3-dicarboxyaldehyde to give 5,6-disubstituted indoles. Reaction of this dialdehyde with sulfones afforded thiepino[4,5-b]pyrrole 6,6-dioxides. In contrast, N-methylpyrrole- 3,4-dicarboxyaldehyde yielded solely the thiepino[4,5-c]pyrroles or the 6,6-dioxides. Mancini and colleagues effected a Diels-Alder reaction between 2- and 3-nitropyrroles and activated dienes to form indoles in modest yields. Fujii and Ohno employed gold in a catalyzed indole synthesis that involved a formal [4 + 2] reaction between pyrroles and 1,3-diynes. The initial C-2 adduct can be isolated and further converted to the indole; carbazoles were formed from indoles under these conditions." @default.
- W2912595994 created "2019-02-21" @default.
- W2912595994 creator A5049245360 @default.
- W2912595994 date "2016-06-17" @default.
- W2912595994 modified "2023-09-23" @default.
- W2912595994 title "Miscellaneous Indole Syntheses from Pyrroles" @default.
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- W2912595994 doi "https://doi.org/10.1002/9781118695692.ch64" @default.
- W2912595994 hasPublicationYear "2016" @default.
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