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• W2912609711 abstract "Frustrated Lewis pairs (FLPs) of Lewis acid (LA) B(C6F5)3 and Lewis base hydrosilane [SiH] have been utilized to promote controlled polymerization of a challenging β-substituted Michael acceptor, methyl crotonate (MC), devoid of chain transfer side reactions. Mechanistic studies show that chain initiation involves LA-catalyzed 1,4-hydrosilylation of MC with [SiH] via FLP-type activation, generating a silyl ketene acetal nucleophile that participates in chain propagation via classic LA activation of monomer and a bimolecular conjugate addition mechanism. The role of the LA is conflicting in the two different catalytic cycles: the FLP activation in chain initiation requires LA-substrate (monomer) dissociation (or weak interaction) while the classic LA activation in chain propagation demands LA-monomer association (or strong interaction)." @default.
• W2912609711 created "2019-02-21" @default.
• W2912609711 creator A5018137652 @default.
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• W2912609711 date "2019-03-01" @default.
• W2912609711 modified "2023-10-12" @default.
• W2912609711 title "Borane/silane frustrated Lewis pairs for polymerization of β-substituted Michael acceptors" @default.
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• W2912609711 doi "https://doi.org/10.1016/j.tet.2019.02.019" @default.
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