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- W2912654150 abstract "Abstract Despite the known nucleophilic nature of [M(CF 3 ) 2 ] − (M=Cu, Ag, Au) complexes, their participation in trifluoromethylation reactions of aryl halides remains unexplored. Here, for the first time, selective access to a [Cu(CF 3 ) 2 ] − species is reported, which is ubiquitous in Cu‐mediated trifluoromethylations, and we rationalize its complex mechanistic scenario as well as its behavior compared to its silver and gold congeners through a combination of experimental and computational approaches." @default.
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- W2912654150 date "2019-03-26" @default.
- W2912654150 modified "2023-10-10" @default.
- W2912654150 title "Exploring the Role of Coinage Metalates in Trifluoromethylation: A Combined Experimental and Theoretical Study" @default.
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- W2912654150 doi "https://doi.org/10.1002/chem.201900496" @default.
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