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- W2912668234 abstract "Abstract The discovery of inverse vulcanization has allowed stable polymers to be made from elemental sulfur, an unwanted by-product of the petrochemicals industry. However, further development of both the chemistry and applications is handicapped by the restricted choice of cross-linkers and the elevated temperatures required for polymerisation. Here we report the catalysis of inverse vulcanization reactions. This catalytic method is effective for a wide range of crosslinkers reduces the required reaction temperature and reaction time, prevents harmful H 2 S production, increases yield, improves properties, and allows crosslinkers that would be otherwise unreactive to be used. Thus, inverse vulcanization becomes more widely applicable, efficient, eco-friendly and productive than the previous routes, not only broadening the fundamental chemistry itself, but also opening the door for the industrialization and broad application of these fascinating materials." @default.
- W2912668234 created "2019-02-21" @default.
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- W2912668234 date "2019-02-07" @default.
- W2912668234 modified "2023-10-18" @default.
- W2912668234 title "Catalytic inverse vulcanization" @default.
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- W2912668234 doi "https://doi.org/10.1038/s41467-019-08430-8" @default.
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