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- W2912690030 endingPage "861" @default.
- W2912690030 startingPage "849" @default.
- W2912690030 abstract "Chiral organohalides including dichlorodiphenyltrichloroethane (DDT), Hexabromocyclododecane (HBCD) and polychlorinated biphenyls (PCBs) raise a significant concern in the environmental occurrence, fate and ecotoxicology due to their enantioselective biological effects. This review provides a state-of-the-art overview on enantioselective microbial transformation of the chiral organohalides. We firstly summarized worldwide field assessments of chiral organohalides in a variety of environmental matrices, which suggested the pivotal role of microorganisms in enantioselective transformation of chiral organohalides. Then, laboratory studies provided experimental evidences to further link enantioselective attenuation of chiral organohalides to specific functional microorganisms and enzymes, revealing mechanistic insights into the enantioselective microbial transformation processes. Particularly, a few amino acid residues in the functional enzymes could play a key role in mediating the enantioselectivity at the molecular level. Finally, major challenges and further developments toward an in-depth understanding of the enantioselective microbial transformation of chiral organohalides are identified and discussed." @default.
- W2912690030 created "2019-02-21" @default.
- W2912690030 creator A5013976948 @default.
- W2912690030 creator A5039943970 @default.
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- W2912690030 creator A5055470439 @default.
- W2912690030 creator A5086068507 @default.
- W2912690030 creator A5087034173 @default.
- W2912690030 creator A5088008330 @default.
- W2912690030 date "2019-04-01" @default.
- W2912690030 modified "2023-10-17" @default.
- W2912690030 title "Microbial transformation of chiral organohalides: Distribution, microorganisms and mechanisms" @default.
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