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- W2912693827 abstract "Abstract Fluorinated surfactants have comprehensive performance superior to non-fluorinated ones, however, their role as metal corrosion inhibitors is elusive. Herein, two fluorinated surfactants, one bearing a branched chain perfluoro group (BFIS) derived from hexafluoropropene trimer and the other bearing a straight chain perfluorohexanesulfonyl group (SFIS), were synthesized and comparatively investigated for their anticorrosion performance on carbon steel in HCl solution. Potentiodynamic polarization and electrochemical impedance spectroscopy revealed that BFIS possessed a corrosion inhibition efficiency much higher than SFIS (95.7% versus 86.6%), although both have similar minimum aqueous surface activities down to 18.50 mN/m. Surface analyses including contact angle, SEM, and XPS and theoretical calculation evidenced that BFIS formed a more densely packed adsorption layer than SFIS on carbon steel, more efficiently preventing corrosive species from corroding the metal surface. The results proved that by taking advantage of the branched chain perfluoro group as the hydrophobic part, fluorinated surfactants can be used as promising metal corrosion inhibitors with excellent performance." @default.
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- W2912693827 date "2019-04-01" @default.
- W2912693827 modified "2023-10-17" @default.
- W2912693827 title "Branched chain versus straight chain fluorinated surfactant: A comparative study of their anticorrosion performance on carbon steel" @default.
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- W2912693827 doi "https://doi.org/10.1016/j.molliq.2019.02.062" @default.
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