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- W2912698112 abstract "The carbonyl stretching bands of acetone and cyclohexanone were studied in various mixtures of p-cresol and cyclohexane. The results indicate that 1:1 and 1:2 ketone-p-cresol complexes are formed at concentrations of p-cresol less than 0·3 M and that even higher complexes exist at higher concentrations. Formation constants for the 1:1 and 1:2 complexes were determined and used to resolve the observed carbonyl bands into the spectra of the individual complexes. More limited data obtained with other phenols and with ethanol are also presented. The results emphasize the effects of specific interactions on the carbonyl frequencies in these systems. They also show the complex nature of solvent-induced frequency shifts and illustrate the advantages of using mixed solvents to study the shifts." @default.
- W2912698112 created "2019-02-21" @default.
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- W2912698112 date "1962-03-01" @default.
- W2912698112 modified "2023-09-23" @default.
- W2912698112 title "Solvent effects on infrared frequencies—I" @default.
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- W2912698112 doi "https://doi.org/10.1016/s0371-1951(62)80140-4" @default.
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