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- W2912715149 abstract "The electrochemical behavior of samarium (Sm), europium (Eu) and ytterbium (Yb) was investigated in 1-n-butyl-1-methylpyrrolidinium bis (trifluoromethansulfone) imide (BMPTFSI) room temperature molten salt by means of cyclic voltammetry and chronopotentiometry. The solubility of the TFSI− salts of trivalent Sm, Eu and Yb was higher than 0.1 mol dm−3 at room temperature. The redox reactions of Sm(III) / Sm(II), Eu(III) / Eu(II) and Yb(III) / Yb(II) were observed at −1.6, −0.3 and −1.0 V vs. Ag / Ag(I), respectively. In all cases, the electrode reactions were quasi- or irreversible from cyclic voltammetry. The electrodeposition of metallic Sm, Eu and Yb could not be observed within the electrochemical potential window of BMPTFSI. The diffusion coefficients of these trivalent species were estimated to be ~10−8 cm2 s−1 by chronopotentiometry, indicating that their mobility is rather low probably due to the complex formation or the strong coulombic interaction with TFSI−." @default.
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- W2912715149 date "2002-01-01" @default.
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- W2912715149 title "Electrochemical Behavior of Some Lanthanides in Imide Room-Temperature Molten Salt Systems" @default.
- W2912715149 doi "https://doi.org/10.1149/200219.0640pv" @default.
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