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- W2912771063 abstract "Abstract Two series of benzoxazines are synthesized from a set of isomeric monofluorophenols (o-, m-, and p-fluorophenols), two polyetheramines (Jeffamine D230 and D400), and formaldehyde. The chemical structures of the benzoxazines are confirmed by nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy. For m-fluorophenol-based benzoxazines, the two sets of data appeared in the 13C, DEPT-135, and 19F NMR spectra indicate that each product obtained is a mixture of two isomers. The ring-opening polymerization temperatures for ortho, meta, and para isomers in the two series of benzoxazines are in descending order para > ortho > meta. The glass transition temperatures (Tgs) of the resultant polybenzoxazines are in ascending order ortho" @default.
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- W2912771063 date "2019-03-01" @default.
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- W2912771063 title "Synthesis, dynamic mechanical properties, and shape memory effect of polybenzoxazines based on monofluorophenol isomers and polyetheramines" @default.
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- W2912771063 doi "https://doi.org/10.1016/j.polymer.2019.01.048" @default.
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