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- W2912774903 abstract "Overall water splitting is an attractive technology to produce clean hydrogen and oxygen. In this study, we constructed amorphous NixCoy layered double hydroxide (LDH) hybridized with three-dimensional NiCo2O4 to fabricate a core–shell nanowire array on Ni foam (NiCo2O4@NixCoy LDH/NF) as a highly efficient electrocatalyst for overall water electrolysis. By tuning the Ni/Co molar ratio in NixCoy LDH, extremely low overpotentials of 193 mV for oxygen evolution reaction (OER) and 115 mV for hydrogen evolution reaction (HER) at a current density of 10 mA cm–2 can be achieved for the NiCo2O4@Ni0.796Co LDH/NF. Detailed investigations verify that the hybrid structure can increase intrinsic activity of the NiCo2O4@Ni0.796Co LDH/NF and enhance the charge-transfer rate. Moreover, a strong electronic interaction between the heterogeneous elements Ni and Co at the interface of the NiCo2O4 and NixCoy LDH might ultimately influence the catalytic performance." @default.
- W2912774903 created "2019-02-21" @default.
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- W2912774903 date "2019-01-30" @default.
- W2912774903 modified "2023-10-15" @default.
- W2912774903 title "Hybridizing NiCo<sub>2</sub>O<sub>4</sub> and Amorphous Ni<sub><i>x</i></sub>Co<sub><i>y</i></sub> Layered Double Hydroxides with Remarkably Improved Activity toward Efficient Overall Water Splitting" @default.
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- W2912774903 doi "https://doi.org/10.1021/acssuschemeng.8b05044" @default.
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