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- W2912781688 abstract "Abstract The enthalpies of the reactions 1 and 2 have been determined as ΔH = Pt(PPh3)2(CPhCPh)cryst. + HClg → Pt(PPh3)2(Cl)(CPhCHPh)cryst. (1) Pt(PPh3)2(CPhCPh)cryst. + 2HClg → cis-Pt(PPh3)2Cl2cryst. + trans-CHPhCHPhg (2) −90.2 ± 6 and ΔH = −139.0 ± 16 kJ mol−1, respectively; dissociation energies of bonds involving platinum are expressed by the relationship: 41 kJ mol−1 + D(Pt-tolane) = 2D(PtCPhCHPh) = {D1(PtCl) + D2(PtCl)} −350 kJ mol−1" @default.
- W2912781688 created "2019-02-21" @default.
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- W2912781688 date "1975-09-01" @default.
- W2912781688 modified "2023-09-27" @default.
- W2912781688 title "The platinum—carbon bond strength in Pt(PPh3)2(Cl)(CPhCHPh)" @default.
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- W2912781688 doi "https://doi.org/10.1016/s0022-328x(00)91955-7" @default.
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