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- W2912809149 abstract "The pigment Zn1.9Cu0.1SiO4 was obtained by the method of sol-gel synthesis. The crystallization temperature was set at 776 °C, ∆H ≈ -16.3 kJ/mol. Thermal expansion of the individual Zn2SiO4 and Zn1.9Cu0.1SiO4 solid solutions was studied by in situ high-temperature X-ray diffraction. It is shown that the substitution of Zn2+ → Cu2+ does not lead to significant changes in the lattice parameters; in the range from room temperature to 800 °C the structure expands monotonically when heated. The coefficients of volumetric thermal expansion for Zn2SiO4 and Zn1.9Cu0.1SiO4 are αV = 8.05 · 10-6 and 8.81 · 10-6 1/K, respectively. The colorimetric coordinates in the RGB system are 71.8% red, 72.9% green and 79.6% blue, which corresponds to the gray-blue pigment." @default.
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- W2912809149 date "2018-12-24" @default.
- W2912809149 modified "2023-10-16" @default.
- W2912809149 title "Sol-gel synthesis and crystal chemical properties of the pigment Zn<sub>1.9</sub>Cu<sub>0.1</sub>SiO<sub>4</sub>" @default.
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- W2912809149 doi "https://doi.org/10.15826/chimtech.2018.5.4.05" @default.
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