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• W2912830165 abstract "The temperature-dependent IR and Raman spectroscopy has been used to study the phase transitions in manganese-azide frameworks with either dimethylammonium (DMA+) or tetramethylammonium (TMA+) cations which adopt a perovskite-like crystal structure. The phase transition in DMA-analogue seems to be associated with cooperative tilting of MnN6 octahedra and order-disorder of hydrogen bonds while in TMA-analogue it is more complex and composed of several processes, including the motions of both manganese-azide framework and tetramethylammonium cations and their possible coupling. Our results are in agreement with the data received from crystallographic and dielectric measurements in the case of TMA-analogue and we have demonstrated the importance of order-disorder of hydrogen bonds in the case of DMA-analogue which previously has not been taken into account." @default.
• W2912830165 created "2019-02-21" @default.
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• W2912830165 creator A5089001937 @default.
• W2912830165 date "2019-05-01" @default.
• W2912830165 modified "2023-09-24" @default.
• W2912830165 title "The mechanism of phase transitions in azide perovskites probed by vibrational spectroscopy" @default.
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• W2912830165 doi "https://doi.org/10.1016/j.saa.2019.02.027" @default.
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