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• W2912833079 abstract "A vanadium-catalyzed coupling of allenylic alcohols with electrophilic halide sources to form α-halo-α′,β′-unsaturated ketones is described. The process proceeds through a metal enolate formed from the 1,3-transposition of an allenol that is initiated by a cheap and earth-abundant vanadium oxo catalyst. Fluorine, chlorine, and bromine electrophiles can be utilized, and the resulting products can give rise to the introduction of nitrogen, oxygen, sulfur, and iodine nucleophiles α to the ketone through substitution chemistry." @default.
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• W2912833079 date "2019-01-28" @default.
• W2912833079 modified "2023-10-18" @default.
• W2912833079 title "Vanadium-Catalyzed Coupling of Allenols with Electrophilic Halide Sources for the Formation of α-Halo-α′,β′-unsaturated Ketones" @default.
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• W2912833079 doi "https://doi.org/10.1021/acs.orglett.9b00195" @default.
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