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- W2912842329 abstract "Durch Fällungs- und Festköperreaktionen konnten folgende ternären und quaternären Oxide der Elemente Neptunium, Plutonium, Americium und Curium erhalten werden:NpP2O7 (α-ThP2O7-Struktur); AmPO4·0-0,5H2O (LaPO4·0-0,5H2O-Struktur); CmPO4; AmAsO4, PuAsO4 und AmPO4 (CePO4-Struktur); PuNbO4, AmNbO4, CmNbO4, AmTaO4 und CmTaO4 (β-Fergusonittyp); PuTaO4 (PrTaO4-Typ); (Pu0,5, Pa0,5)O2, (Am0,5, Pa0,5)O2 und (Cm0,5, Pa0,5)O2 (Fluoritstruktur); Ba(Me0,5, X0,5)O3 (X Nb, Ta, Pa; Me Pu, Am mit geordneter Perowskitstruktur) sowie AmNbTiO6 und AmTaTiO6 (Priorittyp). Die Verbindungen sind isotyp mit den ternären oder quarternären Oxiden der Seltenen Erden mit ähnlichem Ionenradius. Die Existenz von (Ac0,5, Pa0,5)O2 konnte mittels radiochemischer Methoden nachgewiesen werden.Darstellungsbedingungen, chemische Eigenschaften und Gitterkonstanten der angegebenen Verbindungen werden diskutiert.The following compounds of neptunium, plutonium, americium and curium could be obtained by precipitation or solid state reactions:NpP2O7 (α-ThP2O7-structure); AmPO4·0-0,5H2O (LaPO4·0-0,5H2O-structure); CmPO4, AmAsO4, PuAsO4 and AmPO4 (CePO4-structure); PuNbO4, AmNbO4, CmNbO4, AmTaO4 and CmTaO4 (β-fergusonite-type); PuTaO4-(PrTaO4-type); (Pu0,5, Pa0,5)O2, (Am0,5, Pa0,5)O2 and (Cm0,5, Pa0,5)O2 (CaF2-structure); Ba(Me0,5,X0,5)O3 (Me Pu, Am; X Nb, Ta, Pa with ordered perovskite structure) as well as AmNbTiO6 and AmTaTiO6 (Priorite-type). These compounds are mostly isotypic with the compounds of Rare Earth Elements having the same ionic radius. The existence of (Ac0,5, Pa0,5)O2 could be established by radiochemical methods.Reaction conditions, chemical properties, and lattice constants of the above mentioned compounds are discussed." @default.
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- W2912842329 date "1966-04-01" @default.
- W2912842329 modified "2023-10-16" @default.
- W2912842329 title "The antiferromagnetism of uranium monophosphide" @default.
- W2912842329 doi "https://doi.org/10.1016/0038-1098(66)90010-x" @default.
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