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• W2912850160 abstract "Reducing gas contaminants by affordable and effective adsorbents is a major challenge in the 21 st century. In the present study, thorium metal organic framework (Th‐MOF) nanostructures are introduced as highly efficient adsorbents. These compounds were manufactured via a novel route resulting from the development of microwave assisted reverse micelle (MARM) and ultrasound assisted reverse micelle (UARM) methods. The products were characterized utilizing XRD, SEM, TGA/DSC, BET, and FT‐IR analyses. Based on the results, the samples synthesized by MARM had uniform size distribution, high thermal stability, and significant surface area. Calculations using DFT/B3LYP indicated that the compounds have a tendency to the polymeric form, which could theoretically confirm the formation of Th‐MOF. Results of analysis of variance (ANOVA) showed that synthesis parameters played a critical role in the manufacturing of products with distinctive properties. Response surface methodology (RSM) predicted the possibility of creating Th‐MOF adsorbents with the surface area of 2579 m 2 /g, which was a considerable value in comparison with the properties of other adsorbents. Adsorption studies showed that, in the optimum conditions, the Th‐MOF products had high adsorption capacity for CO and CH 4 . It is believed that the synthesis protocol developed in the present study and the systematic studies conducted on the samples which lead to products with ideal adsorption properties." @default.
• W2912850160 created "2019-02-21" @default.
• W2912850160 creator A5047423980 @default.
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• W2912850160 date "2019-02-12" @default.
• W2912850160 modified "2023-10-18" @default.
• W2912850160 title "A novel microwave assisted reverse micelle fabrication route for Th (IV)-MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH₄ adsorption: Design, and a systematic study" @default.
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• W2912850160 doi "https://doi.org/10.1002/aoc.4816" @default.
• W2912850160 hasPublicationYear "2019" @default.
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