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- W2912889016 abstract "Abstract Determination of the vibrational frequency of the ZnBr radical has been elusive, having previously been reported as 220 cm−1 and 318 cm−1 by different investigators. Recently, Burton and Ziurys reported a rotational spectrum of ZnBr from which they were able to estimate a harmonic frequency of 284 cm−1 and an anharmonicity of 1.0 cm−1. In this communication, we report a direct measurement of the vibrational spacing of ZnBr by anion photoelectron spectroscopy of ZnBr−. We determine the neutral vibrational frequency to be 280 ± 5 cm−1 (ωexe = 1.5 ± 0.5 cm−1) and the anion vibrational frequency to be 120 ± 10 cm−1. In addition, we measure the electron affinity of the neutral radical to be 2.45 ± 0.06 eV, and determine that the bond dissociation energy of the anion is lower than that of the neutral by 0.91 ± 0.06 eV." @default.
- W2912889016 created "2019-02-21" @default.
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- W2912889016 date "2019-03-01" @default.
- W2912889016 modified "2023-09-27" @default.
- W2912889016 title "Vibrationally resolved photoelectron spectrum of ZnBr−" @default.
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- W2912889016 doi "https://doi.org/10.1016/j.jms.2019.02.003" @default.
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