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• W2912900214 abstract "Communesins, isolated from the mycelium of a strain of Penicillium sp., are cytotoxic heptacyclic indole alkaloids bearing a bis-aminal structure and two contiguous quaternary carbon centers. Toward a total synthesis of communesin F, we synthesized a pentacyclic ABCDG ring skeleton via carboborylation of 1,3-diene and a Friedel–Crafts-type cyclization, resulting in the formation of an azepine ring through a Bi(OTf)3-catalyzed SN2’ reaction." @default.
• W2912900214 created "2019-02-21" @default.
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• W2912900214 date "2019-02-13" @default.
• W2912900214 modified "2023-10-14" @default.
• W2912900214 title "Synthesis of the ABCDG ring skeleton of communesin F based on carboborylation of 1,3-diene and Bi(OTf)3-catalyzed cyclizations" @default.
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• W2912900214 doi "https://doi.org/10.1038/s41429-019-0142-7" @default.
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