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• W2912942756 endingPage "2839" @default.
• W2912942756 startingPage "2833" @default.
• W2912942756 abstract "Three new acentric Sc-based borates, K6ACaSc2(B5O10)3 (A = Li, Na, Li0.7Na0.3; space group R32), have been obtained and characterized. They are isostructural, and all exhibit three-dimensional [Sc2(B5O10)3]9– anionic architecture composed of B5O10 clusters and ScO6 octahedra with the alkali- and alkaline-earth-metal cations occupying the cavities and keeping the charge balance. These compounds possess moderate second-harmonic-generation (SHG) responses (∼0.2×β-BaB2O4 at 532 nm and ∼0.4×KH2PO4 at 1064 nm) with phase-matching abilities and importantly display short cutoff edges below 200 nm. Furthermore, the relationship between the crystal structure and the SHG property has also been discussed based on the theoretical calculations." @default.
• W2912942756 created "2019-02-21" @default.
• W2912942756 creator A5038670239 @default.
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• W2912942756 date "2019-01-28" @default.
• W2912942756 modified "2023-10-10" @default.
• W2912942756 title "K₆ACaSc₂(B₅O₁₀)₃ (A = Li, Na, Li_0.7Na_0.3): Nonlinear-Optical Materials with Short UV Cutoff Edges" @default.
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• W2912942756 doi "https://doi.org/10.1021/acs.inorgchem.8b03479" @default.
• W2912942756 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30689366" @default.
• W2912942756 hasPublicationYear "2019" @default.
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