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- W291296224 abstract "The title compound, C17H17NO3, crystallizes with four independent molecules (A, B, C and D) in the asymmetric unit. The independent molecules exist as pseudo-inversion-related pairs (A/B and C/D). The A/B set form sheets parallel to the bc plane, and the C/D set stack alternately in sheets, oblique to the ac plane along the b axis. The crystal packing is stabilized by an extensive array of C—H⋯O intermolecular hydrogen-bonding interactions, linking the inversion-related pairs in inversion-related stacks, as well as by π–π stacking interactions between the pyrano rings [A/B and C/D; 3.4738 (15) and 3.6424 (16) Å] and benzo rings [A/A, B/B, C/C and D/D; 3.6142 (15), 3.6152 (16), 3.6442 (16) and 3.6682 (16) Å] and between the pyrano and benzo rings [D/D; 3.9704 (16) Å] of the independent molecules. The two six-membered rings within the quinolizine group of the A/B and C/D molecules adopt envelope and half-chair conformations, respectively." @default.
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- W291296224 date "2007-08-17" @default.
- W291296224 modified "2023-10-03" @default.
- W291296224 title "10-Acetyl-2,3,6,7-tetrahydro-1<i>H</i>,5<i>H</i>,11<i>H</i>-1-benzopyrano[6,7,8-<i>ij</i>]quinolizin-11-one" @default.
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- W291296224 doi "https://doi.org/10.1107/s1600536807039621" @default.
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