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- W2912981240 abstract "Abstract Three-phase vapor-liquid-aqueous (VLA) equilibria can frequently appear in hydrocarbon reservoirs. The presence of the aqueous phase, which can commonly exist as a pure water phase, can dramatically increase the probability of encountering convergence issues in the three-phase equilibrium calculation algorithms. The primary reason is that there is a lack of good initial estimates of equilibrium ratios in both stability tests and flash calculations. In this research, we improve the three-phase VLA equilibrium calculation algorithm for water/hydrocarbon mixtures by developing a new scheme for initializing equilibrium ratios as well as a new procedure for three-phase equilibrium calculations. By applying this new initialization scheme, one can securely identify the aqueous-like stationary point on the tangent plane distance function. In our algorithm, convergence problems, which can frequently appear in the flash calculations of three-phase VLA equilibrium calculations, are avoided. We demonstrate the robustness and efficiency of the newly developed algorithm by showing a number of example calculations." @default.
- W2912981240 created "2019-02-21" @default.
- W2912981240 creator A5017707460 @default.
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- W2912981240 date "2019-05-01" @default.
- W2912981240 modified "2023-09-27" @default.
- W2912981240 title "Improved three-phase equilibrium calculation algorithm for water/hydrocarbon mixtures" @default.
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- W2912981240 doi "https://doi.org/10.1016/j.fuel.2019.02.026" @default.
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