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- W2913113497 abstract "Covalent organic frameworks (COFs) are a class of crystalline porous materials utilized in various potential applications. However, the development of hollow-structured COFs with defined morphology is important for their further applications, which is rare. Herein, COF with unique hollow shuttle morphology was prepared by a Schiff condensation reaction between 4-(4-aldehyde phenyl)ethylene (TPE) and tetra-(4-aminophenyl) porphyrin (TAP). A detailed mechanistic investigation reveals that an initial self-assembly followed by a similar inside-out Ostwald ripening process is responsible for the hollow capsule formation. The hollow microshuttle-shaped capsule COF is used for studying hemoglobin adsorption, which shows an uptake of 550.82 mg g-1 of hemoglobin. These studies could foreshadow new avenues for the development of porous materials with defined morphologies for the adsorption of biomolecules." @default.
- W2913113497 created "2019-02-21" @default.
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- W2913113497 date "2019-01-01" @default.
- W2913113497 modified "2023-10-11" @default.
- W2913113497 title "A hollow microshuttle-shaped capsule covalent organic framework for protein adsorption" @default.
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- W2913113497 doi "https://doi.org/10.1039/c8tb02870b" @default.
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