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- W2913140912 abstract "Structure of molten CaCl2-KCl mixtures with the compositions of 1:1, 1:2, and 1:3 as mole ratio of CaCl2 to KCl was investigated by the radial distribution function based on X-ray diffraction intensities and was analyzed by the correlation method. The nearest neighbor distances of Ca2+ -Cl− and K+ -Cl− pairs in the three melts were 2.76–2.78 and 3.08 A, respectively. The first coordination number of the K+ -Cl− pair was ca. 4 in the three mixtures. On the other hand, the coordination number of the nearest Ca2+ -Cl− pair increased from 5.5 for the 1 : 1 melt to 5.8 for the 1 : 3 melt. Similarly, a slight increase of the nearest Cl− -Cl− distance was observed. These results suggest that the Ca2+ ions surrounded octahedrally by the Cl− ions increase with increasing KCl concentration." @default.
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- W2913140912 date "1987-01-01" @default.
- W2913140912 modified "2023-10-17" @default.
- W2913140912 title "X-Ray Diffraction Study of Molten CaCl2-KCl System" @default.
- W2913140912 doi "https://doi.org/10.1149/198707.0175pv" @default.
- W2913140912 hasPublicationYear "1987" @default.
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