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- W2913294871 abstract "The physical and electrochemical properties of a new series of room temperature molten salts (RTMS) based on the aliphatic onium cation and newly developed fluorinated anion, 2,2,2-trifluoro-N-(trifluoromethyl-sulfonyl) acetamide (TSAC), were investigated. The anion had an excellent ability to lower the melting point of small aliphatic onium salts. Almost all the cations, even the symmetric one, formed RTMS with the new anion in the temperature range of our experiments. The asymmetric structure of the new anion may be the cause the lowering of the melting point of the small onium salts. Not only the melting point but also the viscosity of these melts was decreased by about 20~30% compared with the corresponding salts containing bis(trifluoromethyl-sulfonyl)imide (TFSI). On the other hand, the electrochemical windows of the new RTMS based on aliphatic quaternary ammonium were not as wide as that of the corresponding TFSI melt. The reduction of the TSAC anion might determine the cathodic limit of the TSAC melts." @default.
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- W2913294871 date "2002-01-01" @default.
- W2913294871 modified "2023-10-12" @default.
- W2913294871 title "Physical and Electrochemical Properties of Room Temperature Molten Salt Based on Aliphatic Onium Cations and Asymmetric Amide Anion" @default.
- W2913294871 doi "https://doi.org/10.1149/200219.1057pv" @default.
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