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- W2913306239 abstract "For the purpose of further exploring the effect of nonperipherally attached substituents on single-ion magnet (SIMs) performance, tetrasubstituted bis[1,8,15,22-tetrakis(3-pentyloxy)phthalocyaninato]terbium double-deckers, in both the reduced form TbH[Pc(α-OC5H11)4]2 (1) and the neutral form Tb[Pc(α-OC5H11)4]2 (2), were prepared. Single-crystal X-ray diffraction analysis for 2 unambiguously demonstrates the pinwheellike molecular structure with C4 symmetry. Magnetic investigations of the two bis(phthalocyaninato)terbium double-deckers reveal their characteristic SIM nature. 2 exhibits SIM performance superior to that of 1, as revealed by the larger energy barrier of 466 K for the former species and 431 K for the latter species due to the presence of organic radical–f (radical–Tb) interactions. The enhanced SIM performance of 2 in comparison to 1 actually stems from the presence of radical–f interactions and an enhanced ligand field strength. The latter positive factor is indicated by the electrostatic potential around the terbium ion on the basis of density functional theory (DFT) calculations." @default.
- W2913306239 created "2019-02-21" @default.
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- W2913306239 date "2019-02-05" @default.
- W2913306239 modified "2023-10-14" @default.
- W2913306239 title "Bis[1,8,15,22-tetrakis(3-pentyloxy)phthalocyaninato]terbium Double-Decker Single-Ion Magnets" @default.
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- W2913306239 doi "https://doi.org/10.1021/acs.inorgchem.8b02949" @default.
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