Matches in SemOpenAlex for { <https://semopenalex.org/work/W2913328029> ?p ?o ?g. }
- W2913328029 endingPage "904" @default.
- W2913328029 startingPage "894" @default.
- W2913328029 abstract "A series of alkali metal complexes (Li, Na, K) with different fluorinated phenoxo-imine ligands [M{(O-2-(RN═CH)-C6H4}] [R = C6F5; 2,4,6-F3C6H2F3; 2,6-C6H3F2; 2,3-C6H3F2; 2-C6H4F; 2-CF3C6H4CH2; CF3CH2] have been synthesized and fully characterized. By using THF as solvent, suitable crystals for X-ray diffraction analysis were obtained, and the solid state structure of some of the prepared compounds has been determined. This analysis reveals the formation of a C–F bond activation product for the potassium compound with the five-fluorinated ligand. In stronger donor solvents, such as dimethylsulfoxide, this process occurs immediately, independently of the metal used. This C–F activation takes place in a smooth process at room temperature. The nature of this reaction is studied by 1H-DOSY NMR experiments with stoichiometric amounts of DMSO, monitoring the disaggregation process from the initial solution structure to the final activation product. The variation of the number of fluorine atoms and their location..." @default.
- W2913328029 created "2019-02-21" @default.
- W2913328029 creator A5010669760 @default.
- W2913328029 creator A5011679409 @default.
- W2913328029 creator A5017448448 @default.
- W2913328029 creator A5024033008 @default.
- W2913328029 creator A5038587905 @default.
- W2913328029 date "2019-02-06" @default.
- W2913328029 modified "2023-10-08" @default.
- W2913328029 title "Intramolecular C–F Activation in Schiff-Base Alkali Metal Complexes" @default.
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