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- W2913371392 abstract "Abstract The synthesis of different metal pincer complexes coordinating to the chiral PNP ligand bis(2‐((2 R ,5 R )‐2,5‐dimethyl‐phospholanoethyl))amine is described in detail. The characterized complexes with Mn, Fe, Re and Ru as metal centers showed good activities regarding the reduction of several prochiral ketones. Comparing these catalysts, the non‐noble metal complexes produced best selectivities not only for aromatic substrates, but also for different kinds of aliphatic ones leading to enantioselectivities up to 99% ee . Theoretical investigations elucidated the mechanism and rationalized the selectivity. magnified image" @default.
- W2913371392 created "2019-02-21" @default.
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- W2913371392 date "2019-03-05" @default.
- W2913371392 modified "2023-10-10" @default.
- W2913371392 title "Enantioselective Hydrogenation of Ketones using Different Metal Complexes with a Chiral PNP Pincer Ligand" @default.
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- W2913371392 doi "https://doi.org/10.1002/adsc.201801511" @default.
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