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- W2913455199 abstract "The polymer containing fraction of automobile shredder waste was pyrolyzed in molten AlCl3/NaCl, ZnCl2, LiCl/KCl, LiCl/KCl/CuCl and Li2CO3/Na2CO3/K2CO3. Experiments were run at atmospheric pressure at temperatures of 300–575°C without added H2. From bench scale experiments, the yields of gas, oil and solid (char) were determined for each melt. The maximum oil yield was obtained by pyrolysis of the polymer in CuCl containing LiCl/KCl at 500°C. When the pyrolysis time in this melt was increased, the fraction of oil components with a boiling point 200°C increased. The oil was highly aromatic and may be useful as a gasoline blending agent. Comparison of the rates of polymer decomposition in the different melts showed that pyrolysis in molten AlCl3/NaCl gave the most favorable rates. However, in this melt poor oil yields were obtained (~11 % or less by weight), while a relatively large gas yield was obtained (~30 %) which consisted primarily of isobutane. In general, the oil yields obtained by molten salt treatment of this polymer waste are comparable to yields obtained by inert gas pyrolysis of comparable materials at temperatures several hundred degrees higher. In addition, the use of molten salts offers the potential of changing the product spectrum by the appropriate selection of molten salt used for polymer pyrolysis." @default.
- W2913455199 created "2019-02-21" @default.
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- W2913455199 date "1981-01-01" @default.
- W2913455199 modified "2023-09-26" @default.
- W2913455199 title "Pyrolysis of Automobile Shredder Waste in Molten Salts" @default.
- W2913455199 doi "https://doi.org/10.1149/198109.0408pv" @default.
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