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- W2913482305 abstract "Barbaralanes and semibullvalenes are generally fluxional molecules renowned for their exceedingly low Cope rearrangement activation barriers and their close approach to homoaromaticity. The title compounds are unusual in that they do not undergo the Cope rearrangement and are locked as a single tautomer with no evidence whatsoever for the existence of the other “open” tautomer. This total lack of the Cope rearrangement was demonstrated through variable‐temperature 13 C NMR spectroscopy and computational studies. Copyright © 2016 John Wiley & Sons, Ltd." @default.
- W2913482305 created "2019-02-21" @default.
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- W2913482305 date "2016-08-10" @default.
- W2913482305 modified "2023-09-25" @default.
- W2913482305 title "4,6-Barbaralanedicarboxy-2,8-dicarboxylic anhydride and 1,5-dimethyl-4,6-semibullvalenedicarboxy-2,8-dicarboxylic anhydride: examples of unusual barbaralanes and semibullvalenes that do not undergo the Cope rearrangement. They are locked as the closed tau" @default.
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- W2913482305 doi "https://doi.org/10.1002/poc.3622" @default.
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