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- W2913580063 abstract "Changes in the Curie transition temperature of nanoconfined poly(vinylidene fluoride–trifluoroethylene) P(VDF-TrFE) copolymers can have a severe impact on the electroactive behavior and the application range of these materials. Therefore, the origin of the change in the Curie transition temperature requires a profound understanding. In this work, block copolymer self-assembly into a spherical morphology proves to be a viable method to effectively confine P(VDF-TrFE) in three dimensions for studying the effect of nanoconfinement on the Curie transition. Using differential scanning calorimetry and wide-angle X-ray scattering, easily accessible experimental techniques, we follow the crystalline phase transitions, showing that confining P(VDF-TrFE) in a nonpolar polystyrene (PS) or poly(4-tert-butoxystyrene) (PtBOS) matrix results in an increase of the Curie transition upon cooling and heating. However, when a more polar matrix is used to nanoconfine P(VDF-TrFE), the Curie transition temperature is drastically reduced due to surface effects." @default.
- W2913580063 created "2019-02-21" @default.
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- W2913580063 date "2019-02-06" @default.
- W2913580063 modified "2023-10-11" @default.
- W2913580063 title "Pronounced Surface Effects on the Curie Transition Temperature in Nanoconfined P(VDF-TrFE) Crystals" @default.
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- W2913580063 doi "https://doi.org/10.1021/acs.macromol.8b02382" @default.
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