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- W2913616995 abstract "The solubility of alumina was measured experimentally in neutral and basic cryolite melts with a composition range of 3 ≤ cryolite ratio r ≤12.5. Thermodynamic activity probes for Al and Na were developed and used to monitor the melt basicity (log aNaF) and acidity (log aAlF3) for the solubility measurements. The alumina solubility in cryolite melts was modeled thermodynamically in terms of three oxyfluoride solutes over the wide composition range of 1.5 ≤r ≤12.5. In an acidic melt, monoxygen Na2Al2OF6 is the dominant solute. In a less acidic melt, the dioxygen solute Na2Al2O2F4 is dominant. With further increase in melt basicity, another dioxygen solute Na4Al2O2F6 gains importance. The present model describes perfectly the experimentally determined alumina solubility data." @default.
- W2913616995 created "2019-02-21" @default.
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- W2913616995 date "2002-01-01" @default.
- W2913616995 modified "2023-09-25" @default.
- W2913616995 title "Measurement and Modeling of the Alumina Solubility in Cryolite Melts at 1300K" @default.
- W2913616995 doi "https://doi.org/10.1149/200219.0419pv" @default.
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