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• W2913625536 abstract "Understanding nucleation mechanisms of the solid state on an atomic scale is crucial in order to develop new synthesis methods for tailored materials. Here, we use in situ X-ray total scattering to follow the structural rearrangements that take place in the formation of tungsten oxide, all the way from the ionic precursor clusters in solution to the final crystalline nanoparticles. The reaction was performed in water and oleylamine to study the influence of solvent, and in both cases, the clusters present in the precursor solution adopted the well-known α-Keggin polyoxometalate structure. However, despite the similarity between precursor cluster and the final crystallographic phase, the reaction route is highly dependent on the solvent, shedding new light on nucleation mechanisms and their influence of defects in the final oxide structure. In water, the precursor cluster partly rearranges to the tungstate Y cluster before crystallization of tungsten bronze nanoparticles with a large degree of [WO6] disorder along the c direction of the unit cell. In oleylamine, the reaction goes through several steps, including an amorphous phase and an intermediate crystalline pyrochlore phase before forming small, ordered tungsten bronze nanoparticles. The solvent thus affects not only the crystallite size but also the atomic structure of the nanoparticles, which we link to the observed reaction mechanism." @default.
• W2913625536 created "2019-02-21" @default.
• W2913625536 creator A5051563985 @default.
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• W2913625536 date "2019-02-06" @default.
• W2913625536 modified "2023-10-18" @default.
• W2913625536 title "Mechanisms for Tungsten Oxide Nanoparticle Formation in Solvothermal Synthesis: From Polyoxometalates to Crystalline Materials" @default.
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• W2913625536 doi "https://doi.org/10.1021/acs.jpcc.8b12395" @default.
• W2913625536 hasPublicationYear "2019" @default.
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